Ozonation of a landfill leachateevaluation of toxicity removal and biodegradability improvement

Resumo

This work shows an evaluation of treatments for the leachate produced at the Gramacho Municipal Landfill in Rio de Janeiro state. Brazil. This leachate has very peculiar characteristics, with a high salinity level and very low biodegrability (BOD(5)/COD of 0.05). A sequence of processes was employed in the treatment of this leachate. Initially, a physicochemical treatment was used. while the second stage consisted of application of ozone to improve the biodegradability of the leachate. The final stage comprised a biological treatment. The physical-chemical treatment led to COD and DOC removal levels of 40 and 25 %, respectively, with the use of Al(2)(SO(4))(3). The sequence, of treatments proposed brought good results, with an increase in the BOD(5)/COD ratio from 0.05 to 0.3 after ozonation. The toxicity tests performed using Brachydanio rerio and Poecilia vivipara showed that the toxicity of the leachate had hardly been reduced by ozonation. These results are in agreement with the fact that, despite the higher BOD(5)/COD ratio, the biological process did not present a good perfomance. The total average removal levels of COD and DOC achieved using the combined treatment were 73 and 63 %. respectively, for an ozone dose of 3.0 g L(-1) by the leachate. (C) 2004 Elsevier B.V. All rights reserved.

Ficha do documento

Tipo

Artigo científico

Ano

2005

Instituição

Elsevier Science Bv

Fonte

Repositório da FGV

Idioma

Inglês

Acesso

Acesso restrito

DOI

10.1016/j.jhazmat.2004.09.022

Identificador

oai:repositorio.fgv.br:10438/23056

Temas

Economia

Palavras-chave

OzoneLandfill leachateBiodegadabilityBiological treatmentToxicityChemical oxidationWaste-waterBiodegradávelEconomiaCamada de ozônioLixo